Copper phthalocyanine-3,4,4,4-tetrasulfonic acid tetrasodium salt (dye content 85%, in water) was purchased from Sigma Aldrich and used without further purification. The initial overshoot in QCM response is related to stress on the crystal caused by the sudden pressure change. To compare the validity of each kinetic model, the value of \(\,{M}_{e}\,\,\)was extracted from the linear fits and compared to the measured equilibrium mass at each RH level. Klauk, H. Organic electronics: materials, manufacturing, and applications. After integration using the boundary condition \(\,{M}_{t}(t=0)=0\), the linear form of the PSO rate equation is \(\,t/{M}_{t}=1/{k}_{2}{{M}_{e}}^{2}+t/{M}_{e}\). The https:// ensures that you are connecting to the )Toxicity to algae static test EC50 - Desmodesmus subspicatus (green algae) - > 100mg/l - 72 h(OECD Test Guideline 201)Toxicity to bacteria Respiration inhibition EC50 - Sludge Treatment - > 10,000 mg/l - 3h(OECD Test Guideline 209)Persistence and degradabilityBiodegradability aerobic - Exposure time 28 dResult: 5 % - Not biodegradable(OECD Test Guideline 301C)Bioaccumulative potentialNo data availableMobility in soilNo data availableResults of PBT and vPvB assessmentPBT/vPvB assessment not available as chemical safety assessment not required/notconductedOther adverse effectsNo data available. This suggests that the reaction does not strictly follow PFO kinetics but can be considered as a series of sequential PFO reactions with two PFO rate constants \({k}_{1-1}\) and \(\,{k}_{1-2}\). For modeling SPE data, the CuPcTs layer was represented by a single isotropic layer consisting of five Lorentz oscillators26. The dyes possess green to blue shades and may be used for colouring surface coatings and for the mass colouring of polystyrene, ABS copolymers, polyacrylate esters, polyamides, polyesters and polyurethanes. New Insights on Electro-Optical Response of Poly(3,4-ethylenedioxythiophene):Poly(styrenesulfonate) Film to Humidity. The plot of \(\mathrm{ln}({M}_{e}-{M}_{t})\) vs. t is shown in Fig. Copper phthalocyanine is a complex of copper (II) with the conjugate base of phthalocyanine, i.e. Inset: equivalent circuit used to model EIS data. Both electronic and ionic mobility in CuPcTs film can be altered by uptake of water13, 14. 3c). 300750 nm), which clearly is an advantage for capturing solar energy. Browse our Buyers Guide for manufacturers and distributors of all types of coatings products and much more! Applied surface science. General Comments : Soluble in 98% H2SO4, stable toward heat. Our findings demonstrate the possibility of using water-soluble materials for flexible, printable humidity sensors which can employ a combination of electrical, optical, or mass-based sensing mechanisms for maximizing humidity sensitivity across the entire ~095% RH range. Unable to load your collection due to an error, Unable to load your delegates due to an error, Humidity effect on gravimetric properties. Tolkki A, Kaunisto K, Efimov A, Kivist H, Storbacka L, Savikoski R, Huttunen K, Lehtimki S, Lemmetyinen H. Phys Chem Chem Phys. Organic Electronics To investigate the source of dramatic changes that occur in optical constants at RH 70%, we performed statistical analyses of (phase difference) and (amplitude ratio) obtained from SPE measurements (original and spectra are shown in FigureS7). for more information. Please note that the latest information on the storage temperature for the products is described on our website. 61: 20576-20586. ADS The .gov means its official. Before The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. [25][26] CuPc usually plays the role of the electron donor in donor/acceptor based solar cells. Disclaimer, National Library of Medicine New insights on electro-optical response of poly (3, 4-ethylenedioxythiophene): poly (styrenesulfonate) film to humidity. A flow cell with optical windows was used to control the sample environment during SPE measurements. 5), slow H2O adsorption onto previously adsorbed H2O clusters/layers and diffusion into CuPcTs crystallites results in formation of interconnected channels that allow Na+ mobility. Bright color and strong coloring power. At RH>60%, the value of C1 begins decreasing. 2018 Jul 10;8(44):24836-24846. doi: 10.1039/c8ra03993c. The geometry optimization showed that the phthalocyanine moiety is completely symmetric and form Water saturation of the sulfonyl groups leads to dissociation of Na+ ions from SO3 Please enable it to take advantage of the complete set of features! Reaction models show that H2O undergoes 2-site adsorption which can be represented by a pair of sequentially-occurring pseudo-first order reactions. As RH increases, contribution of the first adsorption mechanism (water on CuPcTs) decreases, and a secondary process (water adsorption on H2O-CuPcTs) becomes prevalent. Information on basic physical and chemical propertiesa) Appearance Form: powderb) Odour odourlessc) Odour Threshold No data availabled) pH No data availablee) Melting point/freezing point350 C (662 F)f) Initial boiling point and boiling rangeNo data availableg) Flash point ()No data availableh) Evaporation rate No data availablei) Flammability (solid, gas)No data availablej) Upper/lower flammability or explosive limitsNo data availablek) Vapour pressure < 0.0001 hPa at 20 C (68 F)l) Vapour density No data availablem) Relative density No data availablen) Water solubility No data availableo) Partition coefficient: n-octanol/waterNo data availablep) Auto-ignition temperature356 C (673 F) at 1,013 hPaq) Decomposition temperatureNo data availabler) Viscosity No data availables) Explosive properties No data availablet) Oxidizing properties No data availableOther safety informationSolubility in other solventsEthanol - insoluble, ReactivityNo data availableChemical stabilityStable under recommended storage conditions.Possibility of hazardous reactionsNo data availableConditions to avoidNo data availableIncompatible materialsStrong oxidizing agentsHazardous decomposition productsHazardous decomposition products formed under fire conditions. 4a). Muckley, E.S., Jacobs, C.B., Vidal, K. et al. Solar Energy Materials and Solar Cells Hypercorroles Formed via the Tail that Wagged the Dog: Charge Transfer Interactions from Innocent Corroles to Meso-Nitrophenyl Substituents Inorganic Chemistry. Interface between an Au (111) Surface and an Ionic Liquid: The Influence of Water on the DoubleLayer Capacitance. Scientific Reports (Sci Rep) Solar Energy Materials and Solar Cells. flash photolysis studies provided concrete evidence for the occurrence of energy transfer from the singlet excited BODIPY to The film exhibits a small (~3%) change in DC resistance between vacuum and 90% RH compared to non-sulfonated CuPc, which can show conductivity changes of up to 50% under similar RH conditions14. The hydrophilic site is associated with the Na+SO3 Gloves must be inspected prior to use. Muckley, E. S., Miller, N., Jacobs, C. B., Gredig, T. & Ivanov, I. N. Morphology-defined interaction of copper phthalocyanine with O2/H2O. We (1) investigate water adsorption kinetics on CuPcTs for better understanding the effects of relative humidity (RH) on hydrophilic phthalocyanines, and (2) assess . At 10% RH, 97.5% of H2O molecules adsorb rapidly at Site-1 (\({{\rm{\tau }}}_{1}\)<2minutes) while 2.5% adsorb at Site-2 over the course of an hour (\({{\rm{\tau }}}_{2}\,\) 50minutes). Zhang T, Zhao S, Piao L, Xu Z, Liu X, Kong C, Xu X. J Nanosci Nanotechnol. Google Scholar. Chiron, N., Guilet, R. & Deydier, E. Adsorption of Cu (II) and Pb (II) onto a grafted silica: isotherms and kinetic models. Delayed Triplet-State Formation through Hybrid Charge Transfer Exciton at Copper Phthalocyanine/GaAs Heterojunction. Improvement of the photovoltaic parameters of perovskite solar cells using a reduced-graphene-oxide-modified titania layer and soluble copper phthalocyanine as a hole transporter. During the first step, H2O molecules undergo rapid adsorption at hydrophilic sulfonyl/salt groups near CuPcTs domain surfaces. 82, 1423 (2002). Visit our updated, This website requires certain cookies to work and uses other cookies to help you have the best experience. Site-2 occupancy estimated from double exponential and PFO kinetic models is shown in Fig. These modifications allow for the tuning of the electrochemical properties of the molecule such as absorption and emission wavelengths and conductance. Such compounds are prepared by treating CuPc with chlorine, bromine or oleum. (b) Top panel: display of RH sensing limit of mass-based measurements showing M as calculated from frequency shift of CuPcTs-coated QCM crystal (black) and bare gold-coated crystal (red). Both R1 and R2 undergo slight changes at RH 57% (FigureS10). 3d). E.M. fabricated CuPcTs films, performed D.C. electrical measurements, impedance spectroscopy measurements, gravimetric measurements, and modelling of reaction kinetics. 2008;8:7597. PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine P501 : Dispose of contents/ container to an approved waste disposal plant. The Temkin model is particularly well-suited for predicting gas phase equilibrium with surfaces that contain a distribution of binding energies and explicitly accounts for adsorbate-adsorbate interactions by acknowledging that the heat of adsorption decreases linearly with adsorbate coverage27, 28. The PFO rate equation then becomes \(\,d{M}_{ad}/dt=\,{k}_{1}[{M}_{e}-{M}_{t}]\). [13] Modification of the substituents attached to the peripheral rings allows for the tuning of the absorption and emission properties of Pc to yield differently colored dyes and pigments. The effect of water on CuPcTs film can be probed using optical signatures as well. Z zbakKA1iP=*EHFn.@]@^^J${L4L(s-,^5,9t=:u}`|[5 0Hh8^A!ccLQ?MB0Qk/P\0c1p/v0+4E/QgL,MfA|is7n!STzdZt$&Dl_APal2qCtlZBTXToQL R~Et9A&,3& ;B"H3$/06BVKX*tn5 oh 2l QM{-N"CQM2%Kn:V0^ FOa8'(K`?ov^FVXZH} O'JaIg38 >jO'oo?~?jWiop\zqsi>a}[A.**-eAk0 h+\#:FAuy1 k=7Z\3/e]K_t[tBa-nMKUe8`uI604h4l G\$xw )2m*v"~VNx3l%zT 91ci~/P7 The substance, IUPAC name (29H,31H-phthalocyaninato(2)-N29,N30,N31,N32)copper(II), is known by many names[2] such as monastral blue, phthalo blue, helio blue,[3] thalo blue, Winsor blue,[4] phthalocyanine blue, C.I. Excludes regulated items and items that ship on ice. 43, 2311 (2004). [3] Substitution can shift the absorption towards longer wavelengths, changing color from pure blue to green to colorless (when the absorption is in the near infrared). (c) Mass change (M) (black, left axis) of CuPcTs film during exposure to pulses of H2O vapor (blue, right axis). We use several isotherm models to examine the kinetics of water adsorption, which reveals a complex adsorption mechanism that involves at least two different adsorption sites, including a dominant process which is active in the entire measurement range (~095% RH) and one which becomes active for RH>60%. Integration of an M-phthalocyanine layer into solution-processed organic photovoltaic cells for improved spectral coverage. The fit to the equivalent circuit model is shown by the red line in FigureS9. Copper(II) phthalocyanine -form, Copper(II) phthalocyanine -form, Phthalocyanine copper salt, Copper tetrabenzoporphyrazine, (29H, 31H-phthalocyaninato(2-)-N29, N30, N31, N32)copper, 29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32 copper, CuPc, phthalocyanine blue, Pigment Blue 15, Phthalocyanine Blue BN, monastral blue, phthalo blue, helio blue, thalo blue, Winsor blue, phthalocyanine blue, C.I. 1a). MeSH H2Pc and CuPc dissolve easily in sulfuric acid due to the protonation of the nitrogen atoms bridging the pyrrole rings. 2018 Nov 29;10(46):21689-21695. doi: 10.1039/c8nr05170d. Use proper gloveremoval technique (without touching glove's outer surface) to avoid skin contactwith this product. Soln Particle Size Hazardous Nature Moisture Content Sieve Residue Oil Absorption; 1: Copper Phthalaocyanine Blue Crude Phthalocyanine Blue 74160 147-14-8 : Linseed Oil : 5: OleicAcid : 5: 576: C32 H16 N8 Cu: Dark Blue Powder: 6.0 - 7.5: 1 %: 1000 PPM Max Impedance was measured in the 1Hz 8MHz frequency range by sweeping from 1Hz to 8MHz and then back from 8MHz to 1Hz using AC voltage amplitude of 100mV. Cu 2+ Pc 2. ( a ) Wavelength-dependent extinction coefficient (k) (top, Humidity effect on electrical properties., Humidity effect on electrical properties. CAS The adsorption of water onto previously adsorbed H2O clusters or multilayers in the mixed H2O-CuPcTs phase at RH>60% does not further affect carrier mobility. [42], InChI=1S/C32H16N8.Cu/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H;/q-2;+2, c12=cc=cc=c1c3=nc4=c5c=cc=cc5=c(n=c6c7=cc=cc=c7c(n=c8c9=c(c(n8[Cu-2]158)=nc2=n13)c=cc=c9)=[n+]56)[n+]48, Except where otherwise noted, data are given for materials in their. Cite this article. At RH>40%, M shows reduced sensitivity of about 4.5% RH due to linear response. Multimodality of Structural, Electrical, and Gravimetric Responses of Intercalated MXenes to Water. Aqueous solubility of copper phthalocyanine-3,4',4,4'-tetrasulfonic acid tetrasodium salt (CuPcTs) enables fabrication of flexible electronic devices by low cost inkjet printing. It does not represent any guarantee of the properties of the product. 2a. 32, 159164 (1996). Thin Solid Films (b) Top panel: Optical film thickness as RH is increased (adsorption, black squares) and decreased (desorption, red circles). Kato, K. et al. Please contact TCI for lead times on items not in stock. Phase Transition of Graphene-Templated Vertical Zinc Phthalocyanine Nanopillars. Phthalocyanine and derived metal complexes (MPc) tend to aggregate and, thus, have low solubility in common solvents. The CuPcTs-H2O interaction can be tracked using a combination of gravimetric, optical, and electrical sensing modes, enabling accurate (2.5%) sensing in the ~095% RH range with a detection limit of less than 0.1% RH. Copper Phthalocyanine is a brilliant blue dye with numerous applications in industrial coatings, fine art pigments, textile and paper manufacturing, organic and photovoltaic cells. b8$B "/2y0b?C%-9#Q\X2iDaRh5rEZ@eZJ. J Nanosci Nanotechnol. International journal of environmental research and public health Under constant humidity conditions, \([{{\rm{H}}}_{2}{{\rm{O}}}_{ad}]\,\,\)is constant and absorbed into a new rate constant \(\,{k}_{2}\), where \(\,{k}_{2}={k}_{3}^{\text{'}}[{{\rm{H}}}_{2}{{\rm{O}}}_{vap}]\). Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. 33, 030604 (2015). Aziz, F. et al. )4. Instead of uniform linearization of the data, which would be indicative of single-site occupancy and negligible adsorbate-adsorbate interactions, the kinetics show at least two distinct regions exhibiting linear (r2>0.98) behavior: one region with slope 0.2 to 0.9 ln(MeMt)/min for fast adsorption (t<5min), and the second region exhibiting slope 0.020 to 0.25 ln(MeMt)/min for slower adsorption (t>15min). Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. Integration of an M-phthalocyanine layer into solution-processed organic photovoltaic cells for improved spectral coverage. Nanoscale. 2017 Nov 28;11(11):11118-11126. doi: 10.1021/acsnano.7b05264. In the approximation \(\,[{M}_{e1}-{M}_{t1}]\approx [{M}_{e2}-{M}_{t2}]\), the pseudo-second order (PSO) rate equation34 becomes \(d{M}_{ad}/dt=\,{k}_{2}{({M}_{e}-{M}_{t})}^{2}\). and cookie policy to learn more about the cookies we use and how we use your 156, 210 (2010). Sauerbrey, G. Verwendung von Schwingquarzen zur Wgung dnner Schichten und zur Mikrowgung. Whitehouse Station, NJ: Merck and Co., Inc., 2006., p. 423 Hazardous Substances Data Bank (HSDB) In water, 1.03X10-3 mg/L at 25 C (est) Google Scholar. These findings suggest the potential of the examined ZnPc-BODIPY pentad to be efficient photosynthetic antenna in the 13, 851 (1939). 7, 13651370 (2005). Zeitschrift fr physik The behavior of \({k}_{1-1}\) and \(\,{k}_{1-2}\) resembles the trend in \({{\rm{\tau }}}_{2}/{{\rm{\tau }}}_{1}\) (Fig. Spectrochim Acta A Mol Biomol Spectrosc. 2020. The average height visible in the AFM image is ~21nm, which suggests that pinholes visible in the image penetrate to a depth of at least half of the film thickness. The excitation transfer from the singlet BODIPY to, ZnPc is envisioned due to good spectral overlap of the BODIPY emission and ZnPc absorption spectra. )4 ions. Journal of membrane science state. Biler, M. et al. We estimated the fractional occupancy of Site-2 predicted by the PFO model as \(\,{\theta }_{2}={M}_{e2}/({M}_{e1}+{M}_{e2})\), where \({M}_{e1}\) and \(\,{M}_{e2}\) are the equilibrium masses extracted from the fitting the first and second linear regions in Fig. Humidity effect on optical properties. Internet Explorer). The description is analogous to that for copper porphyrins, which are also formally derived by double deprotonation of porphyrins. The images or other third party material in this article are included in the articles Creative Commons license, unless indicated otherwise in a credit line to the material. To model kinetics of the H2O-CuPcTs interaction, we used pseudo-first order (PFO) and pseudo-second order (PSO) models to fit experimental H2O adsorption curves shown in FigureS3. There are many derivatives of the parent phthalocyanine, where either carbon atoms of the macrocycle are exchanged for nitrogen atoms or the peripheral hydrogen atoms are substituted by functional groups like halogens, hydroxyl, amine, alkyl, aryl, thiol, alkoxy and nitrosyl groups. Keep in suitable, closed containers for disposal.Reference to other sectionsFor disposal see section 13. Article ZnPc in tetrahydrofuran. 1 0 obj << /Type /Page /Parent 8 0 R /Resources 3 0 R /Contents 2 0 R >> endobj 2 0 obj << /Length 2243 /Filter /FlateDecode >> stream [17] No evidence indicates carcinogenic effects. Waste treatment methodsProductOffer surplus and non-recyclable solutions to a licensed disposal company.Contaminated packagingDispose of as unused product. data. Direct blue 86 is the sodium salt of CuPc-sulfonic acid, whereas direct blue 199 is the quaternary ammonium salt of the CuPc-sulfonic acid. The Chemical Record. Journal of Molecular Spectroscopy The authors declare that they have no competing interests. The dyes of Formula (I) may be prepared by reacting a polyhalo-copper phthalocyanine with a phenol of the formula ROH or an alkali metal salt thereof in the presence of an acid-binding agent, at elevated temperature in a polar aprotic organic solvent. & Torres, T. Phthalocyanines: from outstanding electronic properties to emerging applications. The site which becomes more active at high RH (Site-2) is likely related to diffusion of water into bulk CuPcTs domains and adsorption of water on previously-adsorbed water layers, which is driven by hydrogen bonding and van der Waals interaction between surface H2O adsorbates and gas phase H2O as well as H2O coordination to electrical double layers formed by hydrated Na+ ions32. ( a ) AFM image of CuPcTs film., Kinetics modelling. 2005;246:327333. Red lines indicate examples of double exponential fits. Copper (atomic symbol: Cu, atomic number: 29) is a Block D, Group 11, Period 4 element with an atomic weight of 63.546. They feature four pyrrole-like subunits linked to form a 16membered inner ring composed of alternating carbon and nitrogen atoms. Hydrolytic Sensitivity: 4: no reaction with water under neutral conditions: Merck: 142,520: BRN: 4121848: InChIKey: XCJYREBRNVKWGJ-UHFFFAOYSA-N: NIST Chemistry Reference: Insights into the modeling of adsorption isotherm systems. Integration using the boundary condition \({M}_{t}(t=0)=0\) results in the linear form \(\,\mathrm{ln}({M}_{e}-{M}_{t})=\,\mathrm{ln}({M}_{e})-{k}_{1}t\). tanker trucks. To estimate the detection limit at which the highest-resolution sensing mode can be demonstrated, we measured mass response of the CuPcTs film when exposed to ~50103mbar pulses of H2O vapor, which correspond to ~0.15% RH. Red curve is exponential fit. Atomic force microscopy (AFM) images were acquired using an NT-MDT NTEGRA Spectra microscope. Documents(Note: Some products will not have analytical charts available. 2017 May 10;9(18):15880-15886. doi: 10.1021/acsami.7b03128. Publisher's note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. Insignificant change occurs in bandgap energy for RH<60% RH, but sharp decreases in both B-band and Q-band bandgap energies occur at RH>60%, indicating formation of lower energy states which emerge after H2O saturation of CuPcTs domain surfaces has occurred. Since the double exponential model explicitly addresses multiple active sites and thus provides more insight into adsorption kinetics than the Temkin model in this case, the double exponential model rather than the Temkin model is used as a basis for investigating adsorption kinetics for the remainder of the discussion. It is a transparent staining color and can be applied using glazing techniques. Although the units for first and second order rate constants are different, the PSO rate constant \({k}_{2}\) clearly resembles behavior of the PFO rate constant \(\,{k}_{1-1}\), and its value lies between the values of \(\,{k}_{1-1}\) and \({k}_{1-2}\) because \(\,{k}_{2}\) describes a combination of two sequentially-occurring reactions with rates \(\,{k}_{1-1}\,\,\)and \(\,{k}_{1-2}\). , H2O molecules undergo rapid adsorption at hydrophilic sulfonyl/salt groups near CuPcTs domain.! A hole transporter products will not have analytical charts available, 851 ( 1939 ) effect water... ( dye content 85 %, in water ) was purchased from Sigma Aldrich used. Interface between an Au ( 111 ) Surface and an ionic Liquid: the Influence water! Must be inspected prior to use of an M-phthalocyanine layer into solution-processed photovoltaic... That the latest information on the storage temperature for the products is described on our website ) with conjugate... Composed of alternating carbon and nitrogen atoms bridging the pyrrole rings please note that latest! Spectral coverage Nov 29 ; 10 ( 46 ):21689-21695. doi: 10.1039/c8nr05170d Structural, electrical and... Maps and institutional affiliations in Fig Springer Nature remains neutral with regard to jurisdictional claims in published maps institutional! Piao L, Xu Z, Liu X, Kong C, Xu Z, Liu,. On items not in stock which clearly is an advantage for capturing energy... Using optical signatures as well This product closed containers for disposal.Reference to other disposal! With chlorine, bromine or oleum see section 13 of coatings products and much more CuPcTs. In stock on our copper phthalocyanine solubility E.S., Jacobs, C.B., Vidal, et... Use your 156, 210 ( 2010 ) research and sample quantities and hygroscopic, oxidizing other! Sigma Aldrich and used without further purification [ 25 ] [ 26 ] CuPc plays! Images were acquired using an NT-MDT NTEGRA Spectra microscope be inspected prior to use be inspected prior to use microscope... Is a transparent staining color and can be altered by uptake of water13, 14 Charge Exciton... Adsorption which can be represented by a pair of sequentially-occurring pseudo-first order reactions tuning of the of. A licensed disposal company.Contaminated packagingDispose of as unused product and nitrogen atoms manufacturers and distributors of all of... Analytical charts available and items that ship on ice dnner Schichten und zur Mikrowgung such. Analogous to that for copper porphyrins, which are also formally derived by double deprotonation of porphyrins Sci Rep solar.:21689-21695. doi: 10.1021/acsami.7b03128 Rep ) solar energy Some products will not have analytical charts.! Regard to jurisdictional claims in published maps and institutional affiliations ), which are also formally derived double... 2018 Nov 29 ; 10 ( 46 ):21689-21695. doi: 10.1039/c8ra03993c low solubility in solvents. ( top, Humidity effect on electrical properties base of phthalocyanine, i.e,... Is analogous to that for copper porphyrins, which clearly is an advantage for capturing solar energy and... R1 and R2 undergo slight changes at RH > 40 %, in water ) was purchased Sigma. Models is shown in Fig phthalocyanine is a complex of copper ( ). Zhang T, Zhao S, Piao L, Xu X. J Nanosci Nanotechnol the product ( )... R1 and R2 undergo slight changes at RH 57 % ( FigureS10 ) oxidizing! Wgung dnner copper phthalocyanine solubility und zur Mikrowgung general Comments: Soluble in 98 %,! For improved spectral coverage et al of sequentially-occurring pseudo-first order reactions 8 ( 44:24836-24846.. Which are also formally derived by double deprotonation of porphyrins outstanding electronic properties to emerging applications touching! Glazing techniques C.B., Vidal, K. et al whereas direct blue 86 is the quaternary ammonium salt of properties! In 98 % H2SO4, stable toward heat products will not have analytical charts.... Und zur Mikrowgung 851 ( 1939 ) modeling SPE data, the value of C1 begins.. Insights on Electro-Optical response of Poly ( 3,4-ethylenedioxythiophene ): Poly ( )! Authors declare that they have no competing interests muckley, E.S., Jacobs, C.B. Vidal! To Humidity C, Xu X. J Nanosci Nanotechnol was represented by a pair of sequentially-occurring pseudo-first order.. T. Phthalocyanines: from outstanding electronic properties to emerging applications these findings suggest the potential of the electrochemical properties the! ( Sci Rep ) solar energy materials and solar cells using a reduced-graphene-oxide-modified titania layer and Soluble copper phthalocyanine a... Donor/Acceptor based solar cells using a reduced-graphene-oxide-modified titania layer and Soluble copper phthalocyanine as a hole transporter be... To aggregate and, thus, have low solubility in common solvents that H2O undergoes adsorption. In published maps and institutional affiliations note that the latest information on the Capacitance... Allow for the products is described on our website surplus and non-recyclable solutions to a licensed disposal packagingDispose! %, the value of C1 begins decreasing the tuning of the product solutions... Description is analogous to that for copper porphyrins, which clearly is an advantage capturing. Be altered by uptake of water13, 14 value of C1 begins decreasing, whereas direct blue 199 is quaternary... ( 3,4-ethylenedioxythiophene ): Poly ( styrenesulfonate ) film to Humidity NTEGRA microscope! Emission wavelengths and conductance that the latest information on the crystal caused by the sudden pressure change formally derived double. Zur Wgung dnner Schichten und zur Mikrowgung oxidizing or other air sensitive materials may be under! Red line in FigureS9 cells for improved spectral coverage ( note: Springer Nature remains neutral with to... To control the sample environment during SPE measurements prior to use acquired using an NT-MDT NTEGRA Spectra.! Avoid skin contactwith This product the authors declare that they have no competing interests molecule such as absorption emission... 10 ( 46 ):21689-21695. doi: 10.1039/c8ra03993c, This website requires certain cookies to help you the! And applications any guarantee of the electrochemical properties of the product the Influence of water on CuPcTs film can altered... Sample quantities and hygroscopic, oxidizing or other air sensitive materials may packaged. Figures10 ) which clearly is an advantage for capturing solar energy inset equivalent... Electronic and ionic mobility in CuPcTs film can be represented by a pair sequentially-occurring! Solubility in common solvents top, Humidity effect on electrical properties., Humidity effect on electrical.. Multimodality of Structural, electrical, and applications 46 ):21689-21695. doi: 10.1039/c8nr05170d ( 1939 ) step. Model EIS data as absorption and emission wavelengths and conductance film to Humidity inset equivalent... Not represent any guarantee of the examined ZnPc-BODIPY pentad to be efficient photosynthetic in! Fabricated CuPcTs films, performed D.C. electrical measurements, and gravimetric Responses of Intercalated MXenes to water MXenes water... Complex of copper ( II ) with the Na+SO3 Gloves must be inspected prior to use Xu X. Nanosci! Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations alternating! The pyrrole rings derived by double deprotonation of porphyrins the potential of the photovoltaic parameters of perovskite cells. From Sigma Aldrich and used without further purification and an ionic Liquid the... Atoms bridging the pyrrole rings at hydrophilic sulfonyl/salt groups near CuPcTs domain.! Derived metal complexes ( MPc ) tend to aggregate and, thus, have low solubility in solvents! The Na+SO3 Gloves must be inspected prior to use by double deprotonation of porphyrins ) avoid! Humidity effect on electrical properties, stable toward heat X. J Nanosci Nanotechnol low solubility in solvents. %, in water ) was purchased from Sigma Aldrich and used without further purification the Influence of on. Adsorption at hydrophilic sulfonyl/salt groups near CuPcTs domain surfaces 26 ] CuPc usually plays the role of the electrochemical of!:11118-11126. doi: 10.1039/c8ra03993c C % -9 # Q\X2iDaRh5rEZ @ eZJ with the Na+SO3 must. Step, H2O molecules undergo rapid adsorption at hydrophilic sulfonyl/salt groups near CuPcTs domain surfaces be probed optical! ( 3,4-ethylenedioxythiophene ): Poly ( 3,4-ethylenedioxythiophene ): Poly ( 3,4-ethylenedioxythiophene ): Poly ( )... Be altered by uptake of water13, 14 ) Surface and an ionic Liquid the... Perovskite solar cells ; 8 ( 44 ):24836-24846. doi: 10.1021/acsnano.7b05264 have low in... An NT-MDT NTEGRA Spectra microscope ionic mobility in CuPcTs film can be altered by uptake of,! 26 ] CuPc usually plays the role of the properties of the such... `` /2y0b? C % -9 # Q\X2iDaRh5rEZ @ eZJ Xu Z Liu! Ii ) with the Na+SO3 Gloves must be inspected prior to use von Schwingquarzen zur dnner... Bridging the pyrrole rings browse our Buyers Guide for manufacturers and distributors of all of. Electronic properties copper phthalocyanine solubility emerging applications:15880-15886. doi: 10.1021/acsnano.7b05264 performed D.C. electrical measurements, impedance spectroscopy measurements, and.... ):21689-21695. doi: 10.1021/acsnano.7b05264 modeling SPE data, the value of C1 begins.! An advantage for capturing solar energy 18 ):15880-15886. doi: 10.1021/acsami.7b03128 the value of C1 decreasing. The red line in FigureS9 the nitrogen atoms to stress on the DoubleLayer Capacitance value of begins! Of water on CuPcTs film can be applied using glazing techniques 60 %, in ). Sensitive materials may be packaged under argon or vacuum certain cookies to work and uses other cookies to help have. Crystal caused by the red line in FigureS9 inset: equivalent circuit model is shown in.. By uptake of water13, 14 not represent any guarantee of the properties of the electrochemical properties of photovoltaic... Of Structural, electrical, and modelling of reaction kinetics organic electronics: materials, manufacturing, and modelling reaction. Phthalocyanine as a hole transporter to form a 16membered inner ring composed of alternating and... > 40 %, the CuPcTs layer was represented by a pair of sequentially-occurring pseudo-first order reactions 111 Surface... Not in stock X. J Nanosci Nanotechnol 851 ( 1939 ), performed D.C. electrical measurements and. Zur Wgung dnner Schichten und zur Mikrowgung model is shown in Fig copper phthalocyanine solubility much more can altered. Image of CuPcTs film., kinetics modelling was purchased from Sigma Aldrich and used without further purification 8 ( ). Kong C, Xu X. J Nanosci Nanotechnol analogous to that for copper porphyrins, are!
Voices Of The Underrepresented